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Isomerism is observed in the polymerization of alkenes when one of the carbon atoms of the double bond is monosubstituted. The polymerization of a monosubstituted ethylene, CH2 CHR (where R is any substituent other than H), leads to polymers in which every tertiary carbon atom in the polymer chain is a stereocenter (or stereogenic center). The

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stereocenter in each repeating unit is denoted as C* in Ia and Ib A stereocenter is an atom bearing substituents of such identity that a hypothetical exchange of the positions of any two substituents would convert one stereoisomer into another stereoisomer Thus, an exchange of the R and H groups converts Ia into Ib and vice versa Each stereocenter C* is a site of steric isomerism in the polymerization of CH2 CHR Each such site in a polymer chain can exhibit either of two different con gurations (Ia or Ib) Considering the main carbon carbon chain of the polymer 2 CHR n to be stretched out CH in its fully extended planar zigzag conformation, two different con gurations are possible for each stereocenter since the R group may be situated on either side of the plane of the carbon carbon polymer chain.

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The result of the Mississippi Bubble, as it is now known, was a profound popular distrust of paper money and of big banks, which had an enduring effect on French finance The country returned to coin, and for the rest of the century French banking was carried on largely by private banks In the same year of 1720 the Bank of England survived the similar South Sea Bubble and dominated English finance throughout the century In 1776 the French government organized the Caisse d Escompte.

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If the plane of the carbon carbon chain is considered as being in the plane of this page, the R groups are located on one side or the other of this plane The two con gurations are usually referred to as R and S, although the Cahn Ingold Prelog priority rules cannot be applied strictly since that requires knowledge of the relative lengths of the two polymer chain segements Without knowledge of the lengths of the polymer chain segments, designation of R and S con gurations can be done only in an arbitrary manner One of the con gurations (Ia or Ib) is designated as R and the other as S The lowercase designations, r and s, are often used in place of the uppercase letters to emphasize this aspect (Other designations of the two con gurations appear in the literature: D and L, d and l, and .

) There are two constitutional repeat units (Sec 1-2c) from a stereochemical viewpoint, one with R con guration for the stereocenter and the other with S con guration for the stereocenter (corresponding to Ia and Ib) These are referred to as the two con gurational base units and have an enantiomeric relationship [IUPAC, 1966, 1981, 1996]..

(discount office) It was modeled somewhat after the Bank of England, but it was not called a bank It loaned its capital to the government at a rate not to exceed 4% and had the power to issue notes payable to bearer (394) It proved a quietly successful and useful institution In 1800, it was succeeded by the Bank of France We have seen that the recorded history of French rentes began in the fifteenth century As early as the reign of Louis XI, 1461 1483, there were forced loans to the Crown, which provided that at maturity lenders, if not paid off, would be reimbursed with rentes at rates varying from 5 to 10% a year The concept of rentes followed naturally from the feudal practice of granting incomes to subjects as a reward for services or in return for material considerations.

The classi cation of a C* in the planar zigzag conformation as chirotopic or achirotopic presents dif culty A stereocenter is chirotopic if it lies in a chiral environment [Eliel and Wilen, 1994; Mislow and Siegel, 1984] A chiral environment is one that is not superposable on its mirror image The literal de nition of the term chirotopic would classify each C* as chirotopic since the two polymer chain segments, and , are not equivalent The nonequivalence of the two chain segments is due to differences in length (There may also be differences in end groups depending on the modes of initiation and termination) However, classi cation of C* as chirotopic implies optical activity, and this is clearly not true from a practical viewpoint Optical activity is a short-range phenomenon with its magnitude determined by the differences in the groups attached to the stereocenter.

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javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

how to print pdf file without preview using java

javascript pdf preview image

javascript pdf preview image

javascript pdf preview image

javascript pdf preview image

how to print pdf file without preview using java

how to print pdf file without preview using java

javascript pdf preview image